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Private internet access slow torrenting1/22/2024 ![]() Trust DNS are private and secure DNS servers that anyone can use.P2P servers that are optimized for fast torrenting speeds (one of the best VPNs for torrenting).Surfshark also offers different types of specialty servers: We also see this server feature with both Surfshark and ExpressVPN. Surfshark runs all servers in RAM-disk mode, which eliminates the need for hard drives and also means no data can ever be stored on a server. Start with their super fast network of around 3,200 servers in 100 countries. This section gives a quick overview of each VPNs feature set. Private Internet Access vs Surfshark features comparisonĪ VPN that doesn’t have the features you need is worthless (to you). There’s a clear winner in this category, and that is Surfshark.Ĭompany and Jurisdiction winner: Surfshark VPN ![]() (We covered this issue more in our NordVPN vs IPVanish comparison.)īased on our research, it also does not look like PIA has undergone third-party audits, unlike Surfshark VPN. For example, we have seen this happen with Lavabit, IPVanish, and RiseUp. Consequently, we do not recommend any US-based VPN, including PIA, due to the security and privacy risks. ![]() There have been many cases of the US government forcing US VPNs or email providers to collect data on users for various investigations. Today, Kape also owns CyberGhost VPN, ZenMate VPN, and most recently, Kape purchased ExpressVPN.Īdditionally, Private Internet Access is based in the United States, which is one of the worst jurisdictions in the world for a privacy-focused business. However, in our investigation of Crossrider and Kape, we learned that Crossrider simply produced a browser development platform, which was then used by malicious third parties to distribute malware. Kape was previously named Crossrider, a company that has often been associated with malware. In 2019 Kape purchased Private Internet Access. Support deteriorated, debt accumulated, and eventually the company founders decided to sell out. However, as we noted in our PIA review, things began to slowly change. Private Internet Access company and jurisdictionįor many years, Private Internet Access had an excellent reputation in the privacy community. Additionally, Surfshark has a strict no-logs policy and also a great track record. The Netherlands is not a member of the infamous 5 Eyes alliance (US, UK, Australia, Canada, and New Zealand). While this is not a great jurisdiction, being located in Europe, it is also not horrible. ![]() The Surfshark VPN has also passed an independent security audit performed by Cure53. We know of no privacy or security violations with this service. Since that time, they have maintained a sterling reputation for providing secure, private VPN services to a large and growing audience. Knowing a bit about the company and jurisdiction they are based in will make it easier to decide if you can trust them. A few VPNs have been found to spy on their users, typically under duress from the government of the jurisdiction where they are based. While in an ideal world a VPN provider would never spy on users and risk the company’s reputation, this most certainly is not an ideal world. However people often forget that their VPN provider could potentially see their traffic. A quality VPN will prevent outsiders from seeing what you are doing online, Using sophisticated encryption techniques, a secure VPN service will prevent outsiders from reading your message traffic. More and more people around the world are using a VPN to protect their online privacy. Company and Jurisdiction for PIA and Surfshark In this comparison of the PIA VPN vs the Surfshark VPN, we’ll find out whether Private Internet Access or Surfshark is the leader in these eight categories: It offers excellent speeds with the WireGuard VPN protocol and comes packed with features. Meanwhile, Surfshark is one of today’s best VPN services and it continues to gain popularity. ![]() A few years ago it was sold off to a company that is often associated with malware and adware (but we’ll explain why more below). It has fallen behind in recent years with performance and features. PIA was once one of the leading VPNs - but a lot has changed. This table highlights the main facts about each VPN: It is also cheaper with the coupon in the table below. Compared to Private Internet Access, Surfshark offers much faster speeds, better apps, more security features, and access to more streaming channels. This comparison guide should help you select the best fit for your needs in 2023.īased on the latest test results, Surfshark was the winner in this comparison. Both of these VPNs are well-known and have lots of users - but we also found some big differences, especially with performance. Today we are testing Surfshark vs PIA (Private Internet Access). ![]()
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Number 2 pencil bic1/22/2024 ![]() ![]() Get stuck into our spectacular stationery supplies today and find that gorgeous new folder or pen that’s going to set you up for success. These 0.7mm mechanical pencils have a medium point thats ideal for. Ainiv 12PCS Eco-friendly Wood & Plastic Free Recycled Rainbow Paper Pencils 2 HB Pencils Number 2 Pencils Erasers Toppers with Pencil Sharpener, Macaron Colored Pencils for School and Office Supplies. Experience smooth, dark writing with BIC Xtra-Smooth No. Whether you’re picking up the basics for the classroom, getting ready to take on revision season or looking for a new rucksack to show off in the hallways we have all the essentials you need to get ready for the new school year. BIC Xtra-Sparkle Number 2 Mechanical Pencils With Erasers (MPLP241-BLK), Medium Point (0.7mm), 24-Count Pack, Cute. Youll have two each in cheery pastel purple. And if that beautiful purple marble notebook with gold foil and sprayed edges just happens to fall into our basket then who are we to say no! You’ll find all the latest fashion trends to fall in love with within our stationery collections.Īs well as catering for those with a love for stationery, we also stock essential school stationery to make refilling your supplies for back to school that little bit easier. This set of BIC Matic Pastel Mechanical Pencils will make the perfect addition to your stationery collection. Our stationery ranges from affordable basics to top-quality brands from the likes of Parker Pens and Moleskine.īut as all stationery addicts know well there’s no way we can do a stationery shop without finding something fun and exciting to add to our desks. Retail Tracking Service/ Actual Unit Product Line Sales (Retail And Commercial Combined)/ Annual 2020).Stationery addicts, notebook nerds and folder fiends rejoice at WHSmith you’ll find lots of exciting stationery designs to give you that giddy new stationery feeling.įor those stocking up their desks with the essentials, we have the pens, paper, pencil cases, rulers, erasers and desk accessories you need to keep working efficiently. 1 selling mechanical pencil* by making the smart choice with BIC Xtra-Strong Mechanical Pencils. Exceptional lead resilience and longevity make these refillable mechanical pencils a great option when taking standardized tests and restocking your school or office supplies. A contrasting clip allows for easy attachment to notebooks, pockets and more, and the vibrantly colorful barrels showcase an on-trend design that livens up writing sessions to complete the fashionable look. ![]() ![]() For neat penmanship, these number two pencils ensure smudge-free writing that erases cleanly. Plus, the lead advances quickly with a simple click of the eraser, so you’re always ready to keep writing. Versatile 0.7mm medium point is ideal for a variety of everyday writing activities. One 24-count pack of BIC Xtra-Sparkle Number 2 Mechanical Pencils With Erasers. 40 count Xtra Life Mechanical Pencils1 Bic Pencil 2.5 wood case pencilsMedium. BIC Xtra Sparkle Mechanical Pencil, 0.7mm, 2 Hard Lead, 2 Dozen (MPLP241-BLK) Make writing fun and easy with BIC Xtra-Sparkly Number 2 Mechanical Pencils With Erasers. BIC Xtra-Sparkle Number 2 Mechanical Pencils With Erasers, Medium Point (0.7mm) 144-Count. The leads never need sharpening and advances quickly and easily. BIC Color Cues Mechanical Pencil Set, Black, Fun Color Pencils for School, Perfect for School Supplies. Each thick lead mechanical pencil in this set offers smooth, clear writing, and best of all - no sharpening is required. BIC Mechanical Pencil Variety Pack, Number 2 Mechanical Pencils With Erasers, Fine Point (0.5mm), Medium Point (0.7mm) and Thick Point (0. BIC Xtra-Sparkle Number 2 Mechanical Pencils With Erasers (MPLP241-BLK), Medium Point (0.7mm), 24-Count Pack. The 0.9mm break-resistant lead is thick and durable, making this pack of mechanical pencils a dependable choice for everyday writing activities. Ticonderoga Wood-Cased Pencils, Pre-Sharpened, 2 HB Soft, Yellow, 30 Count. Keep your writing precise and tidy by using BIC Xtra-Strong Number 2 Mechanical Pencils With Erasers. Buy BIC Evolution Cased Pencil, 2 Lead, Yellow Barrel, 48-Count. 1-48 of 903 results for 'number 2 pencils' Results. ![]()
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Lip sync pencil2d1/22/2024 ![]() ![]() The more layers and frames you have, the less synced the audio will be. There are unfortunate yet deep tech reasons for this but it all boils down to: Some apps call this intermediate file or process: playblast, proxy preview or cached pre-render. That said other apps work around this by implementing an intermediate “preview” window with pre-rendering techniques that shows a real-time, but low-res version of the animation. This happens with every other software as well. Pencil2D audio is not currently going to sync during playback regardless of what you do. This process however often takes a bit to populate the RAM with the cached images, so you often need to play it 2 or 3 times before it plays smoothly (though I don’t know why it takes a few tries tho ) Playback in Pencil2D works by caching about 1024mb (default) worth of images constructed by the layering of each image track, and then plays it back as smoothly as it cans. Other options will only create the layer so you have to follow the steps in…įor more in-depth explanation please read the reply below: Regarding audio delay on playback Option A will create a sound layer and skip to step and automatically. ![]() Press the Layers Plus button on the left part of the timeline widget. Go to the topbar menu File > Import > Soundĭ. How to import sound into Pencil2D Installing Pencil2D / How toĪ. On the other hand the sound sync perception is not exactly a bug, but is also not an ideal situation.įor a tutorial on how to import sounds, and do proper lip sync / sound sync with the audio scrubbing feature please check out this unlisted tutorial I made for another user. If you move the timeline cursor partially over a sound and then go back to the start and press the play button you will only hear the “rest” of the sound. I personally found a bug on the nightly build a few days ago. ![]()
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Ring quick release battery pack1/22/2024 ![]() ![]() A pity the only way to keep the battery pack charged seems to be the solar panel. Will only get the ladder out in the Summer time, as hardwire option still working and dusk till dawn light remains active. Checked again after 6 months (now winter and cold), and D Batteries fully charged still, hardwire connection good, but battery pack fully discharged and NOT being kept charged by the hardwire connection. Initially, all three sources green and active on the app. First learning point was make sure there is no tension on the plug-in adapter when installing the cable brackets, otherwise it fails to register on the app as successfully hard wired. First the default D batteries, then a fully charged battery pack (without solar panel), and finally hardwired using a Ring plug-in adapter. I installed the Ring siren with all three power sources connected. Just wanted to share my experience in the UK. The panel will now be fitted outside quite high up and facing south… will update this over time. ![]() Obviously, the winter months might be more challenging, however, we typically get a bit of sun within a week or two - so I’m hopeful. So, I’m really pleased that just pointing west through glass on mostly cloudy days in middle England the full charge level is soon maintained. Under events I saw entries showing the power level was falling, then the battery pack was being charged, then it would be full. By just having a solar charger inside, looking through double glazing on mostly cloudy days, the battery pack Icon changed to charging. To answer my own question, after 12 days using the dawn till dusk led on the outdoor siren could see a drop in battery pack charge. Is this Icon only for detecting the hardwired voltage, if so how am I supposed to know if the battery is being charged by the solar panel? After two weeks of using the dawn until dusk led and testing the siren and alarm LEDs a few times I was hoping to see something to assure me the solar panel is working. The battery level hasn’t visibly dropped and the ‘power charging’ Icon in device settings doesn’t light up. To learn more about how and for what purposes Amazon uses personal information (such as Amazon Store order history), please visit our Privacy Notice.I have a solar panel connected to my outdoor siren, the question is how do you know if this is working? You can change your choices at any time by visiting Cookie Preferences, as described in the Cookie Notice. Click ‘Customise Cookies’ to decline these cookies, make more detailed choices, or learn more. Third parties use cookies for their purposes of displaying and measuring personalised ads, generating audience insights, and developing and improving products. ![]() This includes using first- and third-party cookies, which store or access standard device information such as a unique identifier. If you agree, we’ll also use cookies to complement your shopping experience across the Amazon stores as described in our Cookie Notice. We also use these cookies to understand how customers use our services (for example, by measuring site visits) so we can make improvements. We use cookies and similar tools that are necessary to enable you to make purchases, to enhance your shopping experiences and to provide our services, as detailed in our Cookie Notice. ![]()
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Dia de los muertos skull mask template1/22/2024 ![]() ![]() Learn more about Día de Muertos, and find out how to make real sugar skulls with our DIY Calaveras de Azúcar instructions. This includes using high-quality paper, storing your. There are a few different methods for preserving dia de los muertos coloring pages. Inspired? Create and share by tagging decorate your own Day of the Dead sugar skull, download and print our free coloring page. Featuring everything from sugar skulls themed designs to dancing skeletons, masks, a guitar and more decorations and symbols of the Mexican culture, there is a wide range of drawings to choose from. And the Day of the Dead isn’t morbid or frightening: It’s a time to remember loved ones with stories, songs, feasts, and community celebrations.Ĭheck out the free printable coloring sugar skull coloring page below for a great Day of the Dead activity. Unlike the skulls we see at Halloween, a Día de Muertos sugar skull isn’t meant to be spooky. Encourage pupils to write Day of the Dead inspired stories or poetry, or get each child to come up with their own design and display them in class. As part of the celebration, they might also wear a Day of the Dead mask or makeup to look like sugar skulls, with bright flowers and patterns. This set of templates in the shape of sugar skull masks can be used for both writing and drawing activities - s imply print and distribute to your students. One of its most recognizable icons is the sugar skull or calavera: a skull made of pressed sugar and decorated with colorful icing.Ĭhildren whose families celebrate Día de Muertos decorate-and eat!-miniature calaveras. I love everything about Halloween, and recently I have become really interested in the DIa de los Muertos. ![]() Day of the Dead, Día de Muertos-a celebration of loved ones who have passed away-originated in Mexico and is observed by many people in the United States. ![]()
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Pdfpen pro 9 vs. 81/22/2024 ![]() ![]() " I PREFER YOUR APP FOR ITS SIMPLICITY, EFFICIENCY, AND OCR." However, just one we found on their platform from S. Unfortunately, there's no proof of any authoritative media review on PDFpen. ZDNet - " If you deal with a lot of PDF files, then PDF Expert is the way to go." IMore - " When people ask for an all-purpose PDF markup and annotation app, I tend to send them to Readdle and PDF Expert."Ĭult of Mac - " PDF Expert is the lightweight, powerful viewer your Mac needs." MacWorld - " Goodbye Preview, hello affordable PDF editing on Mac."ĪppleInsider - " PDF Expert is the most Mac-like and straightforward to use of the major PDF apps." MacStories- " You'll find value in what Readdle has developed in PDF Expert." Techradar - " PDF Expert is a robust and easy-to-use solution for managing business documents." Below are what these media reviews sites are saying about the PDF Expert software PDF Expert is highly known for its productivity and even popular tech news/reviews platforms MacStories, MacWorld, iMore, Techradar, Cult Of Mac, AppleInsider, ZDNet, and The Sweet Setup recommend them. PDF Expert vs PDFpen: Authoritative Media Reviews PDF Expert: App of the year runner-up and Editors' choice by Apple ![]() ![]() Plus, it boasts up to 30 million users globally. Yes, the tool was given App of the year runner-up and Editors' choice by Apple. Unfortunately, only PDF Expert is an award-winning tool in this case. PDF Expert vs PDFpen: Awards & Certificate: PDF Expert: $6.67/month (Billed Yearly) $139.99 (Lifetime one-time payment) The PDF Pro Essentials is billed for $129.95 while the PDF Pro 13 is billed for $179.95. PDFpen, on the other hand, also have two plans & price namely PDF Pro Essentials and PDF Pro 13, and they are billed as a one-time payment. However, the lifetime payment limits you from using the tool across various Apple devices. For PDF Expert, the tool gives you the option to make payments monthly or pay lifetime. PDF Expert and PDFpen have two different plans & prices. PDF Experts and PDFpen are compatible with Mac, iPhone, and iPad. Easily add page numbers, headers, bookmarks, footers, line numbers, and watermarks.įrom the features mentioned above, it's obvious that PDFpen wins in terms of the features offered.Create password-protected PDF documents with up to 256-bit AES encryption.Supports editing of PDF files using iCloud or dropbox to allow it to save on iOS.Create a self-signed certificate and digitally sign PDF files using AATL.Combine related PDF files in just one click.Export edited PDF files in different formats, including.Easily create and edit cross-platform fillable forms conveniently.It recognizes texts in scanned documents, making it for users to search, highlight, and copy them.You can fill out an application or tax forms, add your signature, redact PDF files, and add passwords in just a few clicks.Easily delete, rotate, arrange, and do many more PDF organizational tasks faster.Get your PDF file into any preferred file format, including word, excel, ppt, text, etc.Highlight important texts, add comments, and even add stamps to documents with simple PDF annotation tools.You can find advanced editing options for Mac to modify PDF files by changing texts, adding links, and inserting images quickly.Besides you can even search particular words in your document using a specialized search feature. If you're looking for a PDF tool with great speed in processing and opening PDFs, PDF Experts is a reliable option, as it will allow you to open large files, read articles, and compare two documents easily. ![]() You should read on to find out which of both PDF editors it is. However, one has more functions to offer compared to the other. PDF Experts and PDFpen boast excellent features that make them unique. So, keep reading to find out what these differences are. Although the differences are quite thin, that is what makes one tool better than the other. However, as surprising as it might sound, both tools differ in terms of their characteristics. A Full Comparison Between PDF Expert and PDFpenįrom all that is said above, you could tell that PDF Expert and PDFpen are powerful for handling PDF files on Mac. ![]()
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Jdm honda kings1/22/2024 ![]() ![]() will not allow you to register a JDM car to drive on the road. It is also important to keep in mind that some states in the U.S. ![]() are from the early to late ‘90s and soon will be from the early 2000s. Because of this regulation, many of the JDM cars you see in the U.S. ![]() That being said, there are some considerations that you have to know before you decide that one of these cars is right for you.įor example, before a JDM car can be imported to the United States, it has to be at least 25 years old. It is perfectly legal to own a JDM car in the United States. Their small size and quick responsiveness make them a blast to drive and their unique look gives them a great advantage over the more widely available cars on the market. version often come with JDM cars.įor those who are in the market for a sports car that has the dependability of a Japanese economy car, a JDM vehicle could be the right choice. Things like higher horsepower and turbo systems that may not be available for the U.S. True JDM cars may also have slightly better performance figures than the vehicles made for the United States. market, you are also getting something entirely unique. While you are getting the same reliability of a Japanese vehicle made for the U.S. Slight exterior changes and different engine specs make JDM vehicles a popular collector’s item for people who want something different. such as the Mazda RX-7, Acura NSX, and Mitsubishi Lancer, there are generally some differences that make them highly desirable. While many JDM cars are technically similar to models that can be found in the U.S. Why Do People Buy JDM Cars?Īny car enthusiast who is interested in unique automobiles will probably find something to like about JDM cars. If a car has been made in Japan for use in a different country, it is not considered a JDM vehicle. This is to ensure that the cars comply with the laws of the different markets and that they can be exported to those countries. These vehicles will have similar designs and specifications as the JDM version but often have different names and slight design differences. Some Japanese automakers will create different versions of their cars and SUVs for a wide variety of international markets. With these differences, they will still be subject to the laws of the United States once they are imported and need to comply. Oftentimes, these vehicles will have right-hand drive configurations and may even have different language settings for the navigation and infotainment displays. Japan has different standards for vehicles than North America and this will be reflected in the vehicle’s design and components. If a vehicle is going to be designated with the JDM abbreviation, it has to be specifically designed and built for the Japanese car market. By knowing what you have to do and what the drawbacks and benefits are, you can make the right decision for your needs. Importing a vehicle has some unique challenges that you should understand if you are going to purchase a Toyota Supra, Honda Civic, or Nissan Skyline that has been made in Japan and designed for that region. However, there are some considerations you have to think about before deciding if that is the right choice. ![]() If you are looking for a unique car that has some better performance specs and a higher reliability rating than the ones that are available in the United States, a JDM car could be your best bet. This is why it has become a popular practice to buy JDM cars straight from the country where they were originally designed and built. While these North American versions are similar, many people believe that the models built for the Japanese market are of higher quality and better when it comes to performance. There are many Japanese automakers and most of the time, they build cars that are specifically meant to be used in North America. When speaking about vehicles, the acronym 'JDM' stands for Japanese Domestic Market, which is a way of saying cars that were built for use in Japan instead of the United States car market. ![]()
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![]() ![]() Suppose, to lower its annual transportation cost, Atlanta Inc. Expenses that do not have an established and direct relation with revenueĮxpenses that cannot be tied one-to-one with revenue earned fall under this category For example, purchase of fixed assets. The cost of unsold units ($400,000 = $100 x 4,000 units) would be recognized as an asset in year end balance sheet and will be expensed out as and when they are sold in forthcoming period(s). ![]() Instead, only the cost of units sold ($600,000 = $100 x 6,000 units) will be treated as inventory expense and charged to cost of goods sold account. During the current year, it has managed to sell only 6,000 units of those appliances $125 each.Īs per the expense recognition principle, the entire purchase cost of $1,000,000 would not be expensed out in the current period. ![]() It has imported 10,000 units of kitchen appliances from Pakistan $100 per unit. is a trading company operating in Michigan. Expenses that have a direct relationship with revenueĮxpenses which can be directly traced to related revenue fall under this category for example, inventory expenses. The expenses in a business that we need to record as per expense recognition principle majorly fall under the following three categories: (1). Examples of expense recognition principle The expense recognition principle focuses our attention on the incurrence for booking an expense, and not its payment. The incurrence and payment of an expense both may occur at the same time or at different times. The two key terms in this discussion are “incurrence of expense” and “payment of expense”. If an entity fails to follow the expense recognition principle properly, its financial statements would exhibit misleading numbers and lose their acceptability to key stakeholders. On the other hand, if an expense has actually been incurred but not yet paid, an expense as well as a liability for the same is recorded in the books. For instance, if the cash payment for an expense is made in advance of its actual incurrence, it must be recorded as an asset to be expensed out in future. Since this principle is core to the accrual method, it can’t be ignored while recording transactions under modern double entry accounting.Īll expenses need to be accounted for correctly as they not only impact the profit and loss account (or income statement) but also a number of balance sheet items. When does a business incur an expense? An expense is considered to have been incurred in the period in which the business actually gets benefit from that expense. Thus, their appropriate recording in the books of accounts assumes utmost importance.Įxpense recognition principle states that an expense should be recognized in accounts when it is incurred, irrespective of the timing of its cash payment. Expenses have a bearing on both profitability and financial condition of the business entities. Right from the incorporation stage to operational phase, expansion phase and even at the time of winding up, expenses are incurred on every step of the way. All businesses incur various expenses over time. Expense recognition principle is one of the basic and salient parts of GAAP which lays down the guidelines and rules regarding the recognition of expenses in accounting books of business entities. ![]()
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Santa cruz skateboard rails1/22/2024 ![]() ![]() There is also a 5 Euro Administration Fee added on, please be aware of this when placing an order with us. Santa Cruz Skateboards VX decks are thinner, stronger, and have more pop than standard 7 ply decks featuring 5 plies of North American Maple and 2 layers of Quad X technology. Wooten Alive Hand VX Deck Skateboard Deck 8.5in x 32.2in. 10.34in Winkowski Dope Planet VX Shaped Skateboard Deck. Simply pay it and the parcel will then be released to you. 8.0in Gartland Sweet Dreams VX Skateboard Deck. ![]() They will email you a link to pay when it clears customs. You will have to pay VAT (and maybe a little Duty) to DPD in your country. Santa Cruz Skateboards is one of the classic brands that shaped skateboarding from the early days, to what it is today. Santa Cruz Skateboards Slimline rails feature a new slimmed down shape, improved screws, and mounting holes. Now the UK has left the EU all European Orders are VAT Free. Shop Santa Cruz Slimline Rails - Pink on the Official Santa Cruz Online Store Free Shipping on orders over 79.99 Sign up to our Newsletter for 10 off. Shop a vast selection of skateboards, skate apparel, shoes, and more. We ship to Austria, Belgium, Czech Republic, Denmark, Finland, France, Germany, Italy, Luxembourg, The Netherlands, Poland, Portugal, Republic of Ireland, Spain and Sweden.Įuropean Delivery starts from £9.99 and most orders will be delivered in 2 to 3 days. Santa Cruz Slimline Skateboard Rails - White Add to Wish List. Santa Cruz Skateboard Rails CCS is your go-to retailer for skaters of all levels. Larger items that are over £30.01 = £4.99 Santa Cruz Skateboards Slimline HSR rails Featuring an all new beveled 3D contour shape and new super-fast, durable high density material Americas first. Smaller items that are £30.00 and under = £1.99 Santa Cruz Skateboards Slimline rails feature a new slimmed down shape, improved screws, and mounting holes. The Santa Cruz Slimline rails slide ultra fast while protecting the underside of your deck from getting scuffed up. All orders are shipped the same day with our courier or Royal Mail if the order is placed before 3pm with the exception of Saturdays in which case they will ship out on Monday for delivery on Tuesday. ![]()
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Lithium titanate battery cathode1/22/2024 ![]() ![]() On the basis of our results, the deployment of Li4Ti5O12 and Li7Ti5O12 materials for sulfur-based battery technology is questioned mainly by the lower Li-ion conductivity of the carbonate-passivated surfaces and by the chemical reactivity of Li7Ti5O12 with sulfur molecules, which would lead to self-discharge, with resulting loss of capacity and inferior battery performance. Also, we present a model for the passivation of Li4Ti5O12 and Li7Ti5O12 surfaces by lithium carbonate, addressing both Li-ion mobility at the interface and sulfur reactivity. In this paper, we present an ab initio molecular dynamics study complemented with experimental investigations, offering a novel interpretation for the Li-ion mobility in Li4Ti5O12 and Li7Ti5O12 as well as for the chemical reactivity of these materials with molecular sulfur. Safety performance is related to many factors, such as state of charge, capacity, fabrication of battery, cathode and anode materials, electrolyte, etc. ![]() Lithium titanate (Li4Ti5O12) spinel may be a potential candidate for the fabrication of composite cathodes, due to its mechanical robustness and its high electronic and Li-ion conductivity. Batteries with lithium titanate anodes have been. A viable solution to mitigate this problem is the replacement of the carbon, binder, and electrolyte with a ceramic matrix, with high electronic and ionic conductivity. The cathode has a layered structure and during discharge, lithium ions move from the anode to the cathode. While this type of cell produces good capacity during the early cycles, unwanted reactions with the electrolyte degrade the cathode and anode, making the whole cell not competitive with Li-ion batteries. Lithium Titanate Oxide Li4ti5o12 Lto Powder for Lithium Cathode Battery Material Rechargeable: Chargeable Shape: Square Battery Discharge Rate: High. LiS cells are currently built with metallic lithium as anode, a liquid electrolyte, and a cathode composed of a mixture of sulfur, carbon, and binder. ![]() |